dc.contributor.author | Garavagno, María de los A. | |
dc.contributor.author | Hernández, Federico J. | |
dc.contributor.author | Jara-Toro, Rafael A. | |
dc.contributor.author | Pino, Gustavo A. | |
dc.date.accessioned | 2024-06-29T20:07:02Z | |
dc.date.available | 2024-06-29T20:07:02Z | |
dc.date.issued | 2024-04-02 | |
dc.identifier.citation | Garavagno, F. J. Hernández, R. A. Jara-Toro and G. A. Pino. Understanding the active role of water in laboratory chamber studies of reactions of the OH radical with alcohols of atmospheric relevance. Phys. Chem. Chem. Phys., 2024, 26, 12745 DOI: 10.1039/D3CP05667H | es |
dc.identifier.uri | http://hdl.handle.net/11086/552452 | |
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Enlace autora: https://www.researchgate.net/profile/Maria-De-Los-Angeles-Garavagno/publication/379517439_Understanding_the_active_role_of_water_on_laboratory_chamber_studies_of_reactions_of_the_OH_radical_with_alcohols_of_atmospheric_relevance/links/6613e2603d96c22bc77ae8a0/Understanding-the-active-role-of-water-on-laboratory-chamber-studies-of-reactions-of-the-OH-radical-with-alcohols-of-atmospheric-relevance.pdf | es |
dc.description.abstract | In this work, we studied the reactions of three cyclic aliphatic alcohols with OH at room temperature, atmospheric pressure and different humidities in a Teflon reaction chamber. It was determined that the lower the solubility of the alcohol in water, the larger the effect of the humidity on the acceleration of the reaction. This experimental evidence allows suggesting that the acceleration is due to the reaction of the co-adsorbed reactants at the air–water interface of a thin water film deposited on the Teflon walls of the reaction chamber, instead of between co-reactants dissolved in the water film or due to gas phase catalysis as previously suggested. Therefore, formation of thin water films on different surfaces could have some implications on the tropospheric chemistry of these alcohols in the tropical regions of the planet with high humidity. | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Oxidation of alcohols | es |
dc.subject | OH radical | es |
dc.subject | Laboratory Teflon chambers | es |
dc.subject | Atmospheric relevance | es |
dc.title | Understanding the active role of water in laboratory chamber studies of reactions of the OH radical with alcohols of atmospheric relevance | es |
dc.type | article | es |
dc.description.version | info:eu-repo/semantics/publishedVersion | es |
dc.description.fil | Fil: Garavagno, María de los A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica, Córdoba, Argentina. | es |
dc.description.fil | Fil: Garavagno, María de los A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica. Centro Láser de Ciencias Moleculares, Argentina. | es |
dc.description.fil | Fil: Garavagno, María de los A. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Físico-Química de Córdoba, Argentina. | es |
dc.description.fil | Fil: Garavagno, María de los A. University of Bristol. School of Chemistry, Bristol, United Kingdom. | es |
dc.description.fil | Fil: Hernández, Federico J. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica, Córdoba, Argentina. | es |
dc.description.fil | Fil: Hernández, Federico J. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica. Centro Láser de Ciencias Moleculares, Argentina. | es |
dc.description.fil | Fil: Hernández, Federico J. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Físico-Química de Córdoba, Argentina. | es |
dc.description.fil | Fil: Hernández, Federico J. University College London. Department of Chemistry, London, United Kingdom. | es |
dc.description.fil | Fil: Jara-Toro, Rafael A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica, Córdoba, Argentina. | es |
dc.description.fil | Fil: Jara-Toro, Rafael A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica. Centro Láser de Ciencias Moleculares, Argentina. | es |
dc.description.fil | Fil: Jara-Toro, Rafael A. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Físico-Química de Córdoba, Argentina. | es |
dc.description.fil | Fil: Pino, Gustavo A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica, Córdoba, Argentina. | es |
dc.description.fil | Fil: Pino, Gustavo A. Université de Rennes. Institut de Physique de Rennes, France. | es |
dc.description.fil | Fil: Pino, Gustavo A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica. Centro Láser de Ciencias Moleculares, Argentina. | es |
dc.description.fil | Fil: Pino, Gustavo A. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Físico-Química de Córdoba, Argentina. | es |
dc.journal.city | London | es |
dc.journal.country | United Kingdom | es |
dc.journal.editorial | Royal Society of Chemistry | es |
dc.journal.pagination | 12745-1275 | es |
dc.journal.title | Physical Chemistry Chemical Physics | es |
dc.journal.volume | 26 | es |
dc.identifier.eissn | 1463-9084 | |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2024/cp/d3cp05667h | |
dc.identifier.url | https://www.researchgate.net/profile/Maria-De-Los-Angeles-Garavagno/publication/379517439_Understanding_the_active_role_of_water_on_laboratory_chamber_studies_of_reactions_of_the_OH_radical_with_alcohols_of_atmospheric_relevance/links/6613e2603d96c22bc77ae8a0/Understanding-the-active-role-of-water-on-laboratory-chamber-studies-of-reactions-of-the-OH-radical-with-alcohols-of-atmospheric-relevance.pdf | |
dc.identifier.doi | https://doi.org/10.1039/D4CP01632G | |
dc.contributor.orcid | https://orcid.org/0000-0002-6462-8759 | es |
dc.contributor.orcid | https://orcid.org/0000-0001-7497-9424 | es |
dc.contributor.orcid | https://orcid.org/0000-0002-3837-5161 | es |
dc.contributor.orcid | https://orcid.org/0000-0002-8702-2688 | es |